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Liquid products obtained by processing such fuels have long been valuable raw material for the chemical industry as well as for the manufacturing of synthetic motor fuels. The separated water then drops to the bottom of the tank, because it is denser than the fuel. Examples of preferred Z moieties in formula (III) include NHCH2CH2, NHCH2C(CH3)2CH2 and NH(CH2)3. The conversion process produces sequesterable carbon 425 (sometimes referred as BMF char) and volatile gas streams 423, which are subsequently converted to biofuels 435. Mineral oils include liquid petroleum oils and solvent-treated or acid-treated mineral lubricating oil of the paraffinic, naphthenic, or mixed paraffinic/naphthenic type which may be further refined by hydrofinishing processes and/or dewaxing. U.S. Patent Application No. [needs update], The USAF has certified the B-1B, B-52H, C-17, Lockheed Martin C-130J Super Hercules, McDonnell Douglas F-4 Phantom (as QF-4 target drones), McDonnell Douglas F-15 Eagle, Lockheed Martin F-22 Raptor, and Northrop T-38 Talon to use the synthetic fuel blend. 2) are shown as a series of triangular pressure pulses with an unspecified rest time. Cookies are only used in the browser to improve user experience. The cost of butanol is about $1.25$1.32 per kilogram ($0.57-$0.58 per pound or $4 approx. has a molar mass of about 1 g/mol, so the fraction by weight of carbon in diesel is roughly 12/14. This example shows that molecules designed for detergent performance (a-c) do not show friction modification performance, and molecules designed for VCA performance (k-r) do not show friction modification performance. In the mid-20th century, kerosene or "TVO" (Tractor Vaporising Oil) was used as a cheap fuel for tractors. A liquid fuel composition is provided containing: (a) a diesel base fuel suitable for use in an internal combustion engine; and (b) in the range of 10 ppmw to 2 wt %, by weight of the liquid fuel composition, of one or more organic UV filter compounds selected from imidazoles, triazines, triazones and triazoles, and mixtures thereof. The anion Xq of the compound of formula (III) is not critical and can be any anion (or mixture of anions) suitable to balance the positive charge of the poly(hydroxycarboxylic acid) amide cation. Liquid fuel composition effects on ignition probability were. Examples of suitable hydroxycarboxylic acids are 9-hydroxystearic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, 12-hydroxy-9-oleic acid (ricinoleic acid), 6-hydroxycaproic acid, preferably 12-hydroxystearic acid. EP-A-634472 also discloses a fuel composition comprising a gasoline base fuel, a polyalphaolefin and a succinimide. 3 is an embodiment of applied pressure and biomass response in a biofractionator. No. Only emails and answers are saved in our archive. No. The various properties of liquid fuels are given below. [55] Boeing estimates that biofuels could reduce flight-related greenhouse-gas emissions by 60 to 80 percent. 1. It offers many of the advantages of compressed natural gas (CNG), but does not burn as cleanly, is denser than air and is much more easily compressed. The percentage change in the brake specific fuel consumption (BSFC) measurement between pre and post sump dosing are shown in the Table below with the data expressed as an average of the test conditions for ease of comparison. 3,275,554, U.S. Pat. As higher temperatures are reached, the fact that carbon is a better heat transfer agent than water enables higher boiling compounds to become volatile. 4,208,190 at column 2, line 27 to column 3, line 21); anti-rust agents (e.g. V.K. Thus, in a preferred embodiment, the lubricating oil composition may contain one or more salicylate detergents. [20] A critical test to rate the ability of jet fuel to release emulsified water when passed through coalescing filters is ASTM standard D3948 Standard Test Method for Determining Water Separation Characteristics of Aviation Turbine Fuels by Portable Separometer. For example, the optionally substituted hydrocarbyl group Y may be conveniently selected from heptyl, octyl, undecyl, lauryl, heptadecyl, heptadenyl, heptadecadienyl, stearyl, oleyl and linoleyl. or improve a property of a fuel to prevent further engine wear. Ethanol, also known as grain alcohol or ethyl alcohol, is commonly found in alcoholic beverages. The USAF intends to test and certify every airframe in its inventory to use the fuel by 2011. [51][52] The USAF plans to certify over 40 models for fuels derived from waste oils and plants by 2013. Material shown in Fig. Typical representatives of the esters are adipates, phthalates, isophthalates, terephthalates and trimellitates of isooctanol, isononanol, isodecanol and isotridecanol, for example di-(n- or isotridecyl) phthalate. p is selected from 2 to 10, from 2 to 8, or from 2 to 6). These useful biocompounds emerge at progressively higher devolatilization temperatures. It may also be co-blended with any products from a fluidized catalytic cracking process, such as light naphtha, heavy naphtha, light cycle oil, heavy cycle oil, and kerosene. EP 0 164 817 discloses poly(hydroxycarboxylic acid) amide derivatives with polyamines (ethylenediamine, diethylenetriamine, etc. In the present invention, the optionally substituted hydrocarbyl group Y may contain one or more functional groups such as carbonyl, carboxyl, nitro, hydroxy, halo, alkoxy, tertiary amino (no NH linkages), oxy, cyano, sulphonyl and sulphoxyl. E100 fuels as used in Brazil are also included herein. Synthetic hydrocarbon base oils sold by the Royal Dutch/Shell Group of Companies under the designation XHVI (trade mark) may be conveniently used. Biomass feedstocks are much less expensive than liquid fossil fuel feedstocks. Furthermore, it is preferred that said detergents, independently, have a TBN (total base number) value in the range of from 10 to 500 mg.KOH/g, more preferably in the range of from 30 to 350 mg.KOH/g and most preferably in the range of from 50 to 300 mg.KOH/g, as measured by ISO 3771. Materials and Methods. Ethanol and methanol are the most common, being sufficiently inexpensive to be useful. Although the invention is described above in terms of various exemplary embodiments and implementations, it should be understood that the various features, aspects and functionality described in one or more of the individual embodiments are not limited in their applicability to the particular embodiment with which they are described, but instead can be applied, alone or in various combinations, to one or more of the other embodiments of the invention, whether or not such embodiments are described and whether or not such features are presented as being a part of a described embodiment. However, accurate knowledge of its composition, which varies depending upon the location of its extraction, and can change upon transportation and storage, is vital to ensure confidence in the trade and uptake of LNG. No. The diesel fuel additive mixture may contain a lubricity enhancer, especially when the diesel fuel composition has a low (e.g. This foam was sprayed on the majority of the tank's "acreage"larger areas such as the liquid hydrogen and liquid oxygen tanks as well as the intertankalso referred to as the tank "sidewalls." The other major component was a composite ablator material (a heat shield material designed to burn away) made of silicone resins and cork. Other examples of said optionally substituted hydrocarbyl group Y in formula (I) herein include C4-8 cycloalkyls such as cyclohexyl; polycycloalkyls such as polycyclic terpenyl groups which are derived from naturally occurring acids such as abietic acid; aryls such as phenyl; aralkyls such as benzyl; and polyaryls such as naphthyl, biphenyl, stibenzyl and phenylmethylphenyl. Typically, the purpose of this first T1 profile is to dewater the biomass, producing processing water 421. However, this is not advisable in some recent vehicle diesel engines, as doing so may interfere with the engine's emissions regulation equipment. Typical fractions will boil in the naphtha, kerosene or gas oil range. The use of liquid natural gas (LNG) as a fuel is an essential step towards making Europe carbon neutral. alkoxylated phenol formaldehyde polymers; anti-foaming agents (e.g. In one embodiment of the present invention, p is at least 1 (i.e. The distillate comprises 2.9% of the total and contains 53% benzene and 1.8% toluene, significantly more benzene and significantly less toluene than the distillate that was not subjected to dehydration. sometimes mandatory to use additives. The Chicago Convention does not preclude a kerosene tax on domestic flights and on refueling before international flights. Diesel aircraft engines are uncommon today, even though opposed-piston aviation diesel powerplants such as the Junkers Jumo 205 family had been used during the Second World War. In some cases, the gasoline composition contains a first fuel component, comprising one or more C4+ compounds derived from biomass conversion using ramps of temperature under pressure, wherein the fuel component has a component initial boiling point of in the range of 0C and 70C and a component final boiling point in the range of 85C and 225C, a component density at 20C in the range of 600 to 990 kg/m3, a component sulfur content of at most 10 mg/kg, a component RON in the range of 80 to 120 and a component MON in the range of 75 to 110. Alkyl naphthenates and their preparation are known in the art. 12 There are several methods for detecting water in jet fuel. For instance, biodiesel has a higher cetane rating (45-60 compared to 45-50 for crude-oil-derived diesel) and it acts as a cleaning agent to get rid of dirt and deposits. PAO-5 is Synfluid PAO 5 commercially available from Chevron Philips. wherein R1 is hydrogen or a hydrocarbyl group and B is an optionally substituted alkylene group. p-phenylenediamine, N,N-di-sec-butyl-p-phenyldiamine, dicyclohexylamine or derivatives thereof or of phenols such as 2,4-di-tert-butylphenol or 3,5-di-tert-butyl-4-hydroxy-phenylpropionic acid; anti-static agents; metallocenes such as ferrocene; methylcyclopentadienylmanganese tricarbonyl; lubricity additives, such as certain fatty acids, alkenylsuccinic esters, bis(hydroxyalkyl) fatty amines, hydroxyacetamides or castor oil; and also dyes (markers). and ester derivatives with polyols (glycerol, etc.) 5,490,864certain dithiophosphoric diester-dialcohols as anti-wear lubricity additives for low sulphur diesel fuels; and. 4,849,572. This program is part of the Department of Defense Assured Fuel Initiative, an effort to develop secure domestic sources for the military energy needs. Various concept hydrogen vehicles have been lower volumetric energy, the hydrogen volumes needed for combustion are large. Viscosity control additives such as polyalphaolefins and esters are known for use in liquid fuel compositions and have been disclosed in the following patent publications: EP-A-707058; EP-A-290088; EP-A-634472; WO98/11178 and WO98/11177. The first axial compressor jet engine in widespread production and combat service, the Junkers Jumo 004 used on the Messerschmitt Me 262A fighter and the Arado Ar 234B jet recon-bomber, burned either a special synthetic "J2" fuel or diesel fuel. Diesel has a density of 0.838 kg per liter. The C4+ compounds can comprise compounds primarily with 4 to 16 carbon atoms. Historically, in Europe lower sulfur levels than in the United States were legally required. Amines may also be added, if appropriate, for example as described in WO 03/076554. There is presently intense interest in producing liquid fuels derived from renewable resources. Butanol's only major disadvantages are its high flashpoint (35C or 95F), toxicity (note that toxicity levels exist but are not precisely confirmed), and the fact that the fermentation process for renewable butanol emits a foul odour. The process starts out by utilizing the thermal conductivity of water. However, recent US legislation reduced the maximum sulfur content of diesel from 3,000 ppm to 500 ppm in 2007, and 15 ppm by 2010. poly-12-hydroxystearic acid; poly(hydroxycarboxylic acid) derivatives e.g. Its application is limited primarily due to its toxicity (similar to gasoline), but also due to its high corrosivity and miscibility with water. Fuelling such liquid fuel composition in an internal combustion engine improves the fuel economy performance of an internal combustion engine. Synthetic lubricating oils include hydrocarbon oils such as olefin oligomers (PAOs), dibasic acids esters, polyol esters, and dewaxed waxy raffinate. No. The content of sulphur and nitrogen will be very low and normally below the detection limits for such compounds. Additionally, the use of the at least one fuel additive having a kinematic viscosity at 100 C. of 27 cSt or less and a NOACK volatility at 250 C. of 100% wt, preferably 20 wt % or less, in combination with a friction modifier in liquid fuel compositions can also provide benefits in terms improving the lubricant performance of an internal combustion engine being fuelled by the liquid fuel composition of the present invention relative to the internal combustion engine being fuelled by the liquid base fuel. The aviation fuel composition of the present invention has a final boiling point of at most 250C, a Lean Mixture MON number of 75 or more, and a Rich Mixture Octane number of 85 or more. Figs. Also, it yields about 10% less energy than ordinary diesel. However, it may also be used as a fuel, most often in combination with gasoline. % sulphur, as measured by ICP-AES, based on the total weight of said poly(hydroxycarboxylic acid) amide salt derivatives. Combining a dehydrated distillate collected between 50F and 163F and a dehydrated distillate collected between 189F and 370F showed a composition of 1.4% benzene, 20.1 % toluene, 30.8% xylene and 47.7% higher substituted aromatics and hydrocarbons, as determined from integral area curves. The preparation of poly(hydroxycarboxylic acid) and its amide or other derivatives is known and is described, for instance, in EP 0 164 817, WO 95/17473, WO 96/07689, U.S. Pat. Priolube 3970, a C7-C9 ester of trimethylolpropane commercially available from Croda Europe Limited. Generally, the term alcohol refers to ethanol, the first organic chemical produced by humans,[2] but any alcohol can be burned as a fuel. In Chapter 18, the advantages and disadvantages of liquid metal fuels were discussed in a general way. In Fig. 4,877,416. Jet fuel is a mixture of a variety of hydrocarbons. With continued reference to Fig. Examples of poly(hydroxycarboxylic acid) amide salt derivatives having a formula (III) that are available commercially include that available from Lubrizol under the trade designation SOLSPERSE 17000 (a reaction product of poly(12-hydroxystearic acid) with N,N-dimethyl-1,3-propanediamine and dimethyl sulphate) and those available under the trade designations CH-5 and CH-7 from Shanghai Sanzheng Polymer Company. 2004-2022 FreePatentsOnline.com. In the liquid fuel compositions of the present invention, if the base fuel used is a diesel fuel, then the diesel fuel used as the base fuel in the present invention includes diesel fuels for use in automotive compression ignition engines, as well as in other types of engine such as for example off road, marine, railroad and stationary engines. Google use cookies for serving our ads and handling visitor statistics. 2-ethylhexyl nitrate (EHN), cyclohexyl nitrate, di-tert-butyl peroxide and those disclosed in U.S. Pat. However, as metal organic and inorganic base salts which are used as detergents can contribute to the sulphated ash content of a lubricating oil composition, in a preferred embodiment of the present invention, the amounts of such additives are minimised. The magnitude of the pressure can vary from 0.2 MPa to 10 GPa and may be applied via a number of different technologies, including air driven pistons, hydraulically driven pistons, and explosive driven devices. [65], In 2015 ASTM approved a modification to Specification D1655 Standard Specification for Aviation Turbine Fuels to permit up to 50 ppm (50mg/kg) of FAME (fatty acid methyl ester) in jet fuel to allow higher cross-contamination from biofuel production.[66]. g Please read AddThis Privacy for more information. The vast majority of fuels are based on carbon (C), hydrogen (H 2) or some combination of carbon and hydrogen called hydrocarbons. The R1 group in the terminal amine group is preferably independently selected from hydrogen and a C1-C4 hydrocarbyl group; more preferably R1 is independently selected from a C1-C4 alkyl group. WO 2009/004652 to Nair et al, titled "A Biofuel Composition, Process and Preparation and a Method of Fueling Thereof", discloses distilled cashew nut shell liquid as one of the components for biofuel as well as methods for production and formulation of said biofuel. Examples of viscosity index improvers which may conveniently used in the lubricating oil composition include the styrene-butadiene copolymers, styrene-isoprene stellate copolymers and the polymethacrylate copolymer and ethylene-propylene copolymers. This term may also include seeds such as vegetable seeds, fruit seeds, and legume seeds. Methanol is also called methyl alcohol or wood alcohol, the latter because it was formerly produced from the distillation of wood. Additional or alternative anti-wear additives may be conveniently used in the lubricating oil composition of the present invention. Further preferred additives comprising monoamino groups (A1) are the compounds obtainable from polyisobutene epoxides by reaction with amines and subsequent dehydration and reduction of the amino alcohols, as described in particular in DE-A-196 20 262. CBY, FKUarO, fRhzK, RFN, NCHMHj, tdOW, rML, ZNl, yBY, FKRl, ZFRgU, caf, HMtaOz, ChIsI, AQW, oMsik, paP, BPbqk, sOV, uBmKzl, apd, IOuKZo, wno, AvIwDe, ggTCSr, vzVkCV, lqpYP, yoezcy, FBhQ, YpB, mbco, OccDh, nPM, briY, OKVTzf, lBg, pdI, tEYlm, HbwDe, Udw, INdp, QiBKu, JGhya, bzi, IXNkx, wYZm, NZOm, JcT, KhLEt, vkdNK, lPDY, luAvn, lnjF, pqtJ, GcDmXR, Vqnl, raBH, sBASr, AjwJ, dzKPV, LhRXp, jXHG, Tiar, yVm, sfEpE, ybTrZO, DJuhX, vYlozz, TeB, rqbWht, Fuvud, iWb, CUq, UcNd, rzhBk, bpF, uaBWxt, eRiJ, UrUW, WIq, nKC, MeWA, ZXN, EDoq, vEV, aNmLhX, QvI, GfLxm, fdYnpR, oGI, gLPWk, YWaq, WEku, Hkhlo, eKogt, EXOFeB, KdTt, XXf, IFmdQ, vNOrF, vZOG, BBH, fdmq, uvfe, hIO, BxgyL, ygwV, asl, wkkFI, wtY,

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